Product ID:GENESOLV D SOLVENT (VARIOUS GRADES)
MSDS Date:01/01/1987
FSC:6850
NIIN:00-681-5688
MSDS Number: BFLHY

Emergency Phone: 201-455-2000

Info Phone: 315-487-4990/800-522-8001

Preparer: PRODUCT SAFETY DEPT.

Cage: JO859

Telephone: 201-455-4414

Cage: 1L164

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 43,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and
Chronic:ACUTE-EYE:IRRITATION,DISCOMFORT,TEARING,BLURRING OF
VISION.SKIN:IRRITATION,RASH.INHALATION:MAY CAUSE TEMPORARY NERVOUS
SYSTEM DEPRESSION WITH ANESTHETIC EFFECTS.HIGH CONCENTRATIONS OF
VAPORS MAY CAUSE IRREGULAR PULSE,PALPITATION,ABNORMAL LIVER
FUNCTION OR FATALITY.INGESTION:NOT LIKELY TO BE
HAZARDOUS.CHRONIC-NONE.
Effects of Overexposure:OVEREXPOSURE TO THE VAPORS BY INHALATION MAY
CAUSE DIZZINESS,HEADACHE,CONFUSION,INCOORDINATION AND LOSS OF
CONSCIOUSNESS. EYE AND SKIN IRRITANT.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:SEEK MEDICAL ATTENTION.EYES:FLUSH WITH WATER FOR AT LEAST 15
MINUTES.SKIN:WASH WITH SOAP & WATER.INHALATION:REMOVE TO FRESH
AIR.GIVE CPR/OXYGEN IF NEEDED.**DO NOT GIVE EPINEPHRINE OR SIMILAR
DRUGS**.I NGESTION:CALL A PHYSICIAN IMMEDIATELY.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:680F
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:HALOGENS, HALOGEN ACIDS, AND POSSIBLY
CARBONYL HALIDES SUCH AS PHOSGENE

Spill Release Procedures:VENTILATE AREA - ESPECIALLY LOW PLACES WHERE
HEAVY VAPOR MIGHT COLLECT.REMOVE OPEN FLAMES. USE SELF-CONTAINED
BREATHING APPARATUS FOR LARGE SPILLS OR RELEASES. DIKE SPILLS. PICK
UP LIQUID ON SUITABLE ABSORBENT AND STORE IN SEALED CONTAINERS.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORAGE-STORE IN A DRY,WELL VENTILATED
AREA AWAY FROM HIGH HEAT & FLAMES.DO NOT HEAT ABOVE 125 DEG F.
Other Precautions:KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN.
THIS PRODUCT FOR INDUSTRIAL USE ONLY. AVOID BREATHING VAPORS/MISTS.
AVOID CONTACT WITH EYES AND SKIN.

Respiratory Protection:FOR ADEQUATELY VENTED WORK AREAS, NO RESPIRATORY
PROTECTION IS NEEDED. SELF-CONTAINED BREATHING APPARATUS OR
SUPPLIED AIR RESPIRATOR APPROVED BY NIOSH IS REQUIRED IF A LARGE
SPILL OCCURS OR FOR NON-VE NTED AREAS.
Ventilation:LOCAL EXHAUST WHEN LARGE AMOUNTS ARE RELEASED. FOR LOW
PLACES, USE MECHANICAL VENTILATION.
Protective Gloves:BUTYL
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATHE VAPORS OR MIST.
Supplemental Safety and Health

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:-35C FP
Decomp Temp:Decomp Text:482F,250C
Vapor Pres:290 @ 21C
Vapor Density:6.5
Spec Gravity:1.57
Evaporation Rate & Reference:1.3 (ETHER=1)
Solubility in Water:0.035 %
Appearance and Odor:CLEAR, COLORLESS LIQUID, FAINT ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AL POWDER,FINELY DIVIDED BA,LI SHAVING,POWDER TITANIUM,CHEMICALLY
ACTIVE METALS SUCH AS CA,POWDERED MG,ZN,BERYLLIUM
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES
Hazardous Decomposition Products:MAY DECOMPOSE TO HYDROCHLORIC AND
HYDROFLUORIC ACIDS & CARBONYL HALIDES SCH AS PHOSGENE.

Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF BY A LICENSED
RECLAIMER OR INCINERATION FACILITY. COMPLY WITH LOCAL, STATE AND
FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NOS. F001 AND F002 MAY
APPLY TO WASTE MATERIALS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.